全文获取类型
收费全文 | 204228篇 |
免费 | 14795篇 |
国内免费 | 8226篇 |
专业分类
电工技术 | 9426篇 |
技术理论 | 11篇 |
综合类 | 19742篇 |
化学工业 | 20463篇 |
金属工艺 | 11205篇 |
机械仪表 | 18318篇 |
建筑科学 | 44335篇 |
矿业工程 | 7058篇 |
能源动力 | 5023篇 |
轻工业 | 9393篇 |
水利工程 | 5706篇 |
石油天然气 | 8114篇 |
武器工业 | 2225篇 |
无线电 | 12612篇 |
一般工业技术 | 21908篇 |
冶金工业 | 6196篇 |
原子能技术 | 1165篇 |
自动化技术 | 24349篇 |
出版年
2024年 | 370篇 |
2023年 | 2293篇 |
2022年 | 3978篇 |
2021年 | 5006篇 |
2020年 | 5204篇 |
2019年 | 4123篇 |
2018年 | 3963篇 |
2017年 | 5003篇 |
2016年 | 5578篇 |
2015年 | 6028篇 |
2014年 | 13639篇 |
2013年 | 11155篇 |
2012年 | 14263篇 |
2011年 | 15574篇 |
2010年 | 12785篇 |
2009年 | 13487篇 |
2008年 | 12122篇 |
2007年 | 14486篇 |
2006年 | 12682篇 |
2005年 | 11072篇 |
2004年 | 9012篇 |
2003年 | 8341篇 |
2002年 | 6814篇 |
2001年 | 5696篇 |
2000年 | 4692篇 |
1999年 | 3768篇 |
1998年 | 3018篇 |
1997年 | 2526篇 |
1996年 | 2073篇 |
1995年 | 1740篇 |
1994年 | 1495篇 |
1993年 | 1029篇 |
1992年 | 868篇 |
1991年 | 707篇 |
1990年 | 519篇 |
1989年 | 431篇 |
1988年 | 332篇 |
1987年 | 212篇 |
1986年 | 138篇 |
1985年 | 162篇 |
1984年 | 172篇 |
1983年 | 135篇 |
1982年 | 156篇 |
1981年 | 52篇 |
1980年 | 92篇 |
1979年 | 41篇 |
1978年 | 23篇 |
1976年 | 16篇 |
1975年 | 17篇 |
1959年 | 21篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
21.
《International Journal of Hydrogen Energy》2022,47(57):23909-23918
The hydrogel electrolyte is an important part of safety and development potential in zinc-based energy storage equipment due to its inherent low mechanical strength and voltage decomposition. However, hydrogel electrolytes possess a reduced working life for zinc dendrites growth and a narrow voltage window. In this study, a hydrogel electrolyte prepares by the zwitterionic monomer [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) (MS) and sodium alginate (SA) alleviate these problems. The zwitterionic double-network hydrogel has good mechanical strength, inhibits the growth of zinc dendrites, enhances practicability, greatly increases the voltage window (0–2.4 V), and has self-healing properties to its rich functional groups. The assembled zinc-ion hybrid supercapacitors (ZHSs) have a high-power density of 172.33 W kg?1 and an energy density of 88.56 Wh·kg?1 at 0.5 A g?1. The assembled zinc-ion battery also has good electrochemical performance. Flexible ZHSs and batteries provide power to the timer stably under different bending angles. The zwitterionic double-network hydrogel can be applied to both zinc-based supercapacitors and batteries. 相似文献
22.
《International Journal of Hydrogen Energy》2022,47(81):34504-34532
This paper focuses on thermal destratification and pressurisation inside thermally stratified storage tanks by continuous gas bubbling. The primary purpose of doing these studies is to better understand the effect of bubble dynamics on thermal destratification and quantify the extent of destratification. The volume of fluid and interface compression method of OpenFOAM CFD code is utilised for the present analysis. Different values of inlet gas velocities (Vg), orifice diameters (do), and arrangement of the orifices in triangular and square fashion with different pitches (p/do) are considered. In addition, the effect of gravitational forces (g/ge) on thermal destratification is also reported. For all these cases, the effectiveness of thermal destratification is quantified in terms of a newly defined parameter, the destratification index (Id). For Vg = 1 m/s, the Id value is maximum compared to lower Vg values. It is seen that when the gas velocity increased from 0.3 m/s to 1.0 m/s, the average effectiveness in thermal destratification (Idavg) and pressure at the ullage increased by 44.38% and by 64.81%, respectively. The Idavg and pressure at ullage increased by 96.29% and 14.91%, respectively, when the g/ge ratio changed from 0.3 to 3. Compared to the triangular arrangement with p/do = 10, the calculated Idavg increased by 30.67% when gas inlets were arranged with a square pitch of 10. For p/do = 4, 6 and 8, the increments in Idavg are of the order of 12.86%, 19.43% and 21.92%, respectively, for gas inlets arranged in a square fashion as compared to the triangular arrangement. It is found that continuous bubbling with gas inlets arranged in square pitch p/do = 10 gives higher effectiveness in thermal destratification. Thus, by these studies, one can develop a thermal destratification mechanism with continuous bubbling for optimum performance. Also, these studies give an overall idea of sparger design for getting the correct gas flow rate for thermal destratification within the cryogenic liquid storage tanks. 相似文献
23.
《International Journal of Hydrogen Energy》2022,47(37):16375-16397
Many attempts have been made to improve mass transfer by reducing the size of reactors. However, such reduction will fairly quickly reach practical limitations and numerous difficulties still remain. Catalytic washcoat shape and properties may be critical design factors, but the mechanisms for their effects on mass transfer characteristics are still not fully understood. To effectively eliminate problems associated with mass transport phenomena in microstructured steam-methanol reformers, the effects of washcoat shape and properties were investigated in various situations by performing computational fluid dynamics simulations. The dependence of the solution on mass transfer characteristics was reduced to a small number of dimensionless parameters. A dimensionless mass transfer analysis was carried out in terms of the Sherwood, Schmidt, and pore Reynolds numbers. The results indicated that the rate of mass transfer is predominantly controlled by washcoat properties, and porosity and effective thermal conductivity are fundamentally important. The rate of the reforming reaction is typically controlled by kinetics at a temperature of 480 K and limited by mass transfer at a temperature of 580 K. The shape of washcoats affects the overall mass transfer characteristics, depending on the structural and thermal properties of washcoats. The shape effect is limited by heat transfer. A three-fold increase in effectiveness factor can be achieved by increasing the effective thermal conductivity of the washcoat. Design recommendations were finally made to improve transport characteristics for the systems. 相似文献
24.
《International Journal of Hydrogen Energy》2022,47(71):30472-30483
Efficient electrocatalyst for alkaline oxygen evolution reaction is the critical core to the wide application of metal-air energy storage and water electrolysis hydrogen energy. Therefore, appropriate design of highly active and stable non-noble metal oxygen evolution electrocatalyst with good electronic structure and multilevel structure is both a goal and a challenge. Here, we report a Fe–Ni2P electrocatalyst (NiFeP-MOF) with multilevel structure, which was obtained by anion exchange on the basis of Fe–Ni(OH)2 (NiFe-MOF) grown on nickel foam in situ by solvothermal method. As expected, Fe substitution regulates the Ni oxidation state in the NiFeP-MOF and realizes electronic structure coupling, showing a highly active and stable oxygen evolution reaction (OER) in alkaline electrolyte solution. Specifically, the NiFeP-MOF demonstrates an ultralow overpotentials (232 mV, 10 mA cm?2; 267 mV 100 mA cm?2), respectively, an extremely small Tafel slope (34 mV dec?1). Separately, the electrocatalyst shows an excellent cycle stability at 10 mA cm?2 for 12 h (43,200 s). More importantly, this work come up with an available policy for the preparation of excellent alkaline hydrolysis electrolysis catalysts and air cathodes with excellent performance. 相似文献
25.
为研制车船等壳体所用的轻质、高强复合板材,选用超高分子量聚乙烯(UHMWPE)短纤维纱,制备成单层经纬为120根/(10 cm)的平纹组织,采用多组经纱持续更替交织层的方法制成2L(1+0)型、4L(2+1)型、6L(3+2)型3种多层角联锁结构织物,采用扦插芯棒、模压成型方法制成菱形蜂窝状的热固性环氧树脂基中空板,并与2块真空吸液法制成的面板组成“三合一”复合板,同时测定了复合板材的结构特征及其平拉、平压和弯曲性能。结果表明:3种类型复合板的密度均远小于水的密度,其中6L(3+2)型最小,为0.48 g/cm3;复合板层数越多,环氧树脂越难渗透尤其是在中空板菱形交叉点处,复合板平拉、平压、抗弯曲强度则呈现递增,制成的6L(3+2)型复合板试样平压强度可达到1.03 MPa。 相似文献
26.
通过试验得出了C105混凝土100 mm×100 mm×100 mm立方体非标准试件抗压强度换算系数以及C105混凝土的标准方差和强度变异系数。采用理论计算,得到了棱柱体抗压强度与立方体抗压强度的比值αc1,并与试验实测平均值进行了比较,验证了理论计算方法的可行性。此外,通过对比分析,探讨了直接外延法和引用公式法两种C105混凝土设计参数计算方法的正确性,研究结果可为C105管桩混凝土的设计和应用提供参考。 相似文献
27.
Qian-Yun Han Fang Liu Yuan-Ying Ni 《International Journal of Food Science & Technology》2022,57(2):920-930
The gene sequence coding for the membrane-bound polyphenol oxidase (mPPO) with a length of 1761 bp was cloned by PCR method and shown to contain one highly conserved sequence encoding a di-copper-binding region. The predicted three-dimensional structure of mPPO indicated that the active site was located near two copper ions and composed of a typical bundle of four α-helices. Each of the two catalytic copper ions was coordinated with three histidine residues in the hydrophobic pocket, yielding His 180, His 201, His 210, His 332, His 336 and His 366. Docking studies showed that 4-methylcatechol and chlorogenic acid have different binding models due to different ligand sizes and binding sites in the active centre, and it was found that the smaller compound exhibited a higher affinity for mPPO. Molecular dynamic simulation results indicated that Phe 353 is important in controlling enzymatic activity through influencing substrate coordination in the active site. 相似文献
28.
Our empirical analysis focuses on the effect of regional policies on migration attraction factors in Europe. We employ a regression discontinuity design to assess the causal relationship between the reception of large amounts of public funds and migration flows in the EU-15 regions. In highly-subsidised regions, we find a large increase in the share of foreign citizens from less-developed countries when compared to low-subsidised regions with similar pre-treatment characteristics. The analysis shows that such an increase is due to the positive impact of the European regional policy on job market opportunities as well as the improvement of public goods supply. 相似文献
29.
30.
《中国稀土学报(英文版)》2022,40(4):660-669
The table-like magnetocaloric effect is significant for the magnetic refrigeration applications above 20 K based on the Ericsson cycle. Herein, we prepared a series of Nd6Fe13Pd1–xCux (x = 0.05, 0.1, 0.15) compounds by the arc-melting method. These compounds show the single crystalline phase in the tetragonal Nd6Fe13Si-type structure with the space group I4/mcm. A magnetic phase transition from ferromagnetism to antiferromagnetism and a metamagnetic transition from the antiferromagnetic state to the ferromagnetic state are observed in each of the compounds. The compounds exhibit table-like magnetocaloric effects with large refrigerant capacities. A constant ΔSM in a temperature span of 40 K in the Nd6Fe13Pd0.85Cu0.15 compound are observed. For a field change of 0–5 T, the peak values of –ΔSM for the Nd6Fe13Pd0.95Cu0.05, Nd6Fe13Pd0.90Cu0.10, and Nd6Fe13Pd0.85Cu0.15 compounds are estimated to be 4.8, 4.6 and 4.4 J/(kg·K) with corresponding refrigerant capacity values of 323, 331 and 316 J/kg, respectively. The obtained table-like magnetocaloric effects with large refrigerant capacities as well as fairly small thermal and magnetic hysteresis deem these series of compounds good candidates for single-phase magnetic refrigeration based on the Ericsson cycle. 相似文献